Vulcanization reaction a ɛwɔ peroxide a ɛkorɔn-temperature vulcanized silicone rɔba no kɔ so sɛnea free radical reaction afiri no te. Wɔ ɔhyew tebea mu no, organic peroxides porɔw ma ɛyɛ free radicals, a afei ɛne organic akuw di dwuma wɔ polysiloxane molecules te sɛ methyl ne ethyl akuw mu ma ɛyɛ kɛse-molecular free radicals. Sɛ saa a ɛkorɔn-molecular free radicals no ka wɔn ho wɔn ho bom a, cross-nkitahodi ba.
Peroxide ahorow asia a wɔtaa de di dwuma wɔ hɔ wɔ-temperature vulcanized silicone rɔba mu. Vulcanization tebea ne scopes a ɛwɔ organic peroxides ahorow mu no nyɛ pɛ.
Wɔn a wɔde di dwuma no betumi apaw nnuru a ɛfata sɛnea wɔn ahiade te. Sɛ nhwɛso no,-temperature porɔw a ɛba fam wɔ peroxide ahorow te sɛ di peroxide (2, 4-dichlorobenzene) mu no betumi ama vulcanization dodow a ɛkɔ ntɛmntɛm, na nsu a ɛyɛ hyew a ɛwɔ ne nnuru a aporɔw no mu no sua koraa, enti ɛho nhia sɛ nhyɛso foforo biara ba na ama wɔasiw nsu a ɛwɔ nsu no mu no ano. Enti, wɔtaa de saa aduru yi di dwuma wɔ mframa a ɛyɛ hyew vulcanization extrusion ne molding akwan horow mu. Nanso, esiane sɛ vulcanization ahoɔhare no kɔ ntɛmntɛm nti, charring taa ba bere a wɔtow nneɛma a ɛyɛ tratraa anaasɛ wɔde nsunsu kɔ baabi foforo no. Wɔ tebea horow a ɛtete saa mu no, peroxides a ɛwɔ vulcanization ahoɔhare a ɛyɛ brɛoo te sɛ benzoyl peroxide no fata.
Nanso, saa aduru yi bɛma gas aba bere a wɔreyɛ vulcanization no, enti wontumi mfa mframa a ɛyɛ hyew nyɛ vulcanized. Mmom no, wɔtaa de steam a ɛkɔ so yɛ vulcanization no di dwuma. Ade foforo a ɛyɛ bɔne a ɛwɔ atifi hɔ-a wɔaka ho asɛm no mu-temperature vulcanizing agents ne sɛ, sɛ wɔtow nneɛma a ɛyɛ tratraa a, wɔn nneɛma a ɛyɛ acidic a ɛporɔw no benya nkɛntɛnso bɔne wɔ ɔhyew a ɛwɔ nneɛma no mu no so.
Ɛwom sɛ ɛforo-temperature vulcanizing agents te sɛ Diisopropylbenzene peroxide ne di-TERT-butyl peroxide fata ma methyl raw rɔba a ɛyɛ adwuma kɛse nkutoo de, nanso ɛyɛ vulcanizing nnuru a eye sen biara ma nneɛma a ɛyɛ den na wobetumi nso de adi dwuma wɔ carbon black{3} kɔntɔnkrɔn mu{3} kɔntɔw .